[Ag70(PW9O34)2(tBuCC)44(H2O)2]8+: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions

Zhan-Guo Jiang, Kang Shi, Yu-Mei Lin, Quan-Ming Wang

DOI: 10.1039/c3cc49290g

Journal: Chemical Communications

A silver alkynyl cluster containing a Ag70 shell and two lacunary [PW9O34](9-) templating ions was synthesized by an ionothermal approach and fast core-shell electronic communication between silver(i) centers and polyoxometalates was verified via cyclic voltammetry studies in [BMIm]BF4.

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Journal Info

Journals:

ISSN 1359-7345

Quartile

CategoryQuartile
CHEMISTRY, MULTIDISCIPLINARY2

Quartile(CN)

CategoryQuartile
化学2
化学, 化学综合3
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