Reaction intermediates buried within a solid-liquid interface are difficult targets for physiochemical measurements. They are inherently molecular and locally dynamic, while their surroundings are extended by a periodic lattice on one side and the solvent dielectric on the other. Challenges compound on a metal-oxide surface of varied sites and especially so at its aqueous interface of many prominent reactions. Recently, phenomenological theory coupled with optical spectroscopy has become a more prominent tool for isolating the intermediates and their molecular dynamics. The following article reviews three examples of the SrTiO 3 -aqueous interface subject to the oxygen evolution from water: reaction-dependent component analyses of time-resolved intermediates, a Fano resonance of a mode at the metal-oxide–water interface, and reaction isotherms of metastable intermediates. The phenomenology uses parameters to encase what is unknown at a microscopic level to then circumscribe the clear and macroscopically tuned trends seen in the spectroscopic data.

Tanja Cuk

Annual Review of Physical Chemistry

自 1950 年出版的《物理化学年度评论》涵盖了物理化学领域的重大发展，包括生物物理化学、化学动力学、胶体、电化学、地球化学和宇宙化学、大气和气候化学、激光化学和超快过程，液态、磁共振、物理有机化学、聚合物和大分子等。

The Annual Review of Physical Chemistry, published since 1950, covers significant developments in the field of physical chemistry, including biophysical chemistry, chemical kinetics, colloid chemistry, electrochemistry, geochemistry and cosmochemistry, atmospheric and climate chemistry, laser chemistry and ultrafast processes, liquid state, magnetic resonance, physical organic chemistry, polymers, and macromolecules.

《Annual Review of Physical Chemistry》自1950年出版，涵盖了物理化学领域的重大进展，包括生物物理化学、化学动力学、胶体化学、电化学、地球化学和宇宙化学、大气与气候化学、激光化学与超快过程、液态物质、磁共振、物理有机化学、聚合物及大分子等多个方面。

Category	Quartile
化学	1
化学, 物理化学	1

Phenomenology of Intermediate Molecular Dynamics at Metal-Oxide Interfaces

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Journal Info

Category	Quartile
CHEMISTRY, PHYSICAL	1