Electrochemical Selenized Reaction of N-Arylbicyclo[1.1.0]butane-1-carboxamides: Access to 3-(Arylselanyl)spiro[cyclobutane-1,3′-indolin]-2′-one Derivatives
N-芳基双环[1.1.0]丁烷-1-甲酰胺的电化学硒化反应:合成3-(芳基硒基)螺[环丁烷-1,3′-吲哚啉]-2′-酮衍生物
Jiyao Liu, Yuliang Qian, Haicheng Zhao, Yun Liu, Zhenglong Qin, Zifeng Zhang, Liangce Rong
期刊: The Journal of Organic Chemistry
摘要
A novel selenized reaction of N-arylbicyclo [1.1.0]butane-1-carboxamides with diselenide for the synthesis of polycyclic indoline derivatives is developed under electrochemical conditions. The synthesis is achieved by the bicyclo[1.1.0]butane strain-release reaction and intramolecular cyclization process. In addition, this approach features a wide range of substrates, good group tolerance, shorter reaction time, and mild conditions.
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期刊:
ISSN: 0022-3263
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