1,2,4-Triazole-Based Tunable Aryl/Alkyl Ionic Liquids

基于1,2,4-三唑的可调芳基/烷基离子液体

Dirk Meyer, Thomas Strassner

DOI: 10.1021/jo101784v

期刊: The Journal of Organic Chemistry

摘要

Ionic liquids based on aryl-/alkyl-substituted imidazolium salts constitute a new generation of ionic liquids with a high degree of flexibility. The new concept could now also be extended to aryl-/alkyl-substituted 1,2,4-triazolium salts. The two different phenyl-substituted 1H- and 4H-1,2,4-triazoles have been synthesized by a coupling reaction or a one-pot synthesis with diformylhydrazine, respectively. Reaction with alkyl bromides provided the 1,2,4-triazolium bromides, and an anion-exchange reaction led to the corresponding bis(trifluoromethylsulfonyl)imide salts with melting points well below 100 °C.

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期刊信息

期刊:

ISSN: 0022-3263

国际分区

类目分区
CHEMISTRY, ORGANIC1

国内分区

类目分区
化学2
化学, 有机化学2
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