This work complements our recent discovery of new phases derived from zirconium perchlorate by addition of hydrogen peroxide. Here, we investigate analogous reactions with hafnium perchlorate, which is found to have modifications of the Clearfield–Vaughan tetramer (CVT). For hafnium perchlorate derivatives, we find distorted versions of CVT by X-ray diffraction and study the reaction solutions by SAXS, Raman spectroscopy, and ESI-MS. Furthermore, we investigate mixed Hf–Zr solution and solid phases and find the latter resemble the zirconium family at low Hf concentrations and the hafnium family at higher hafnium contents.

James A. Sommers

Danielle C. Hutchison

Nicolas P. Martin

Lauren Palys

Jenn M. Amador

Douglas A. Keszler

May Nyman

Inorganic Chemistry

无机化学出版无机化学各个阶段​​的基础研究。涵盖范围包括关于结构和热力学、动力学、无机反应机制、生物无机化学以及有机金属化学、固态现象和化学键合理论的相关方面的定量研究的实验和理论报告。重点放在重要的新化合物和已知化合物的合成、结构、热力学、反应性、光谱学和键合特性上。

The journal "Inorganic Chemistry" focuses on fundamental research in the field of inorganic chemistry. It covers quantitative studies related to structure and thermodynamics, kinetics, inorganic reaction mechanisms, bioinorganic chemistry, organometallic chemistry, solid-state phenomena, and chemical bonding theory. The emphasis is on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding characteristics of both important new compounds and known compounds.

《Inorganic Chemistry》期刊专注于无机化学领域的基础研究，涵盖了结构与热力学、动力学、无机反应机制、生物无机化学、有机金属化学、固态现象以及化学键合理论等方面的定量研究。期刊重点关注重要新化合物及已知化合物的合成、结构、热力学、反应性、光谱学和键合特性等内容。

Differentiating Zr/Hf<sup>IV</sup> Aqueous Polyoxocation Chemistry with Peroxide Ligation

This work investigates analogous reactions with hafnium perchlorate, which is found to have modifications of the Clearfield-Vaughan tetramer (CVT), and investigates mixed Hf-Zr solution and solid phases and finds the latter resemble the zirconium family at low Hf concentrations and the hafnia family at higher ha fnium contents.

Category	Quartile
化学	2
化学, 无机化学与核化学	1

Differentiating Zr/Hf^IV Aqueous Polyoxocation Chemistry with Peroxide Ligation

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Journal Info

Category	Quartile
CHEMISTRY, INORGANIC & NUCLEAR	1

Differentiating Zr/HfIV Aqueous Polyoxocation Chemistry with Peroxide Ligation

ivySCI AI Smartly Parses PDF, Answers Researchers' Questions, and Helps You Understand Papers in Seconds

Journal Info

Differentiating Zr/Hf^IV Aqueous Polyoxocation Chemistry with Peroxide Ligation