Variation of the reaction conditions with AgC:CR (R = Ph, t Bu), t BuPO 3 H 2 , (Et 4 N)VO 3 and AgNO 3 as starting materials afforded three isostructural globular neutral silver(I)-ethynide clusters incorporating the [, in which the central cavity of each Ag 16 cluster is occupied by two nitrate ions that function as a template. Furthermore, from the reaction of AgC:C t Bu with (NH 4 ) 4 [V 2 O 4 (d,l-citrate) 2 ]Á4H 2 O, we isolated a new high-nuclearity silver(I)-ethynide cluster [(VO 4 ) 2 @Ag 34 (C:C t Bu) 22 (NO 3 ) 6 ]Á8H 2 O that encapsulates a pair of templating orthovanadate ions.

Yun-Peng Xie

Han Wang

Thomas C. W. Mak

Journal of Cluster Science

该期刊发表以下类型的论文：(A) 原创性和重要研究；(B) 权威综合评论或当前感兴趣主题的简短概述； (C) 关于新的重要研究的简短但紧急的沟通； (D) 旨在促进在不同集群学科工作的研究人员之间交流创新或挑衅性想法并鼓励对话的评论。

The Journal of Cluster Science publishes the following types of papers: (A) Original and significant research; (B) Authoritative comprehensive reviews or brief overviews of current topics of interest; (C) Brief but urgent communications regarding new important research; (D) Comments aimed at fostering the exchange of innovative or provocative ideas among researchers working in different cluster disciplines and encouraging dialogue.

《Journal of Cluster Science》期刊发表以下类型的论文： (A) 原创性和重要的研究； (B) 权威的综合评论或当前热门主题的简要概述； (C) 关于新重要研究的简短而紧急的沟通； (D) 旨在促进不同集群学科研究人员之间交流创新或具有挑战性的想法，并鼓励对话的评论。

Category	Quartile
化学	4
化学, 无机化学与核化学	4

Silver-Ethynide Clusters with Oxovanadate Components

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Journal Info

Category	Quartile
CHEMISTRY, INORGANIC & NUCLEAR	2