The octahedral titanium catalyst Ti(Ph2PNpy)2(NEt2)2 (1) was found to be an efficient catalyst for the hydroamination of methylenecyclopropane with either aromatic or aliphatic amines. For a symmetrical methylenecyclopropane, only one product is obtained in high yield. The reaction of complex 1 with ethylamine and aniline produces the dimeric titanium complexes Ti2(Ph2PNpy)2(μ-NEt)2 and Ti2(Ph2PNpy)2(μ-NPh)2, respectively.

Elena Smolensky

Moshe Kapon

Moris S. Eisen

Organometallics

ORGANICMETALLICS 是有机金属化学的旗舰期刊，记录了最活跃的科学领域之一的进展，将有机化学和无机化学联系起来。该杂志发表文章、通讯、评论和教程（指导性概述），描述了对各种应用（包括催化剂设计和催化过程）的合成、结构、键合、化学反应性和反应机制的研究；主族、过渡金属、镧系和锕系金属化学；高分子科学和材料科学的综合方面；和生物有机金属化学。

Organometallics is the flagship journal of organometallic chemistry, documenting advancements in one of the most active scientific fields that bridges organic and inorganic chemistry. The journal publishes research articles, communications, reviews, and tutorials that describe studies on synthesis, structure, bonding, chemical reactivity, and reaction mechanisms related to various applications, including catalyst design and catalytic processes; the chemistry of main group, transition, lanthanide, and actinide metals; integrated aspects of polymer science and materials science; and bioorganometallic chemistry.

《Organometallics》是有机金属化学领域的旗舰期刊，记录了这一活跃科学领域的最新进展，连接了有机化学与无机化学。该期刊发表研究文章、通讯、评论和教程，涵盖了催化剂设计和催化过程等多种应用的合成、结构、键合、化学反应性和反应机制的研究；涉及主族、过渡金属、镧系和锕系金属的化学；以及高分子科学和材料科学的综合方面；同时也关注生物有机金属化学。

Category	Quartile
化学	3
化学, 无机化学与核化学	2
化学, 有机化学	2

Catalytic Intermolecular Hydroamination of Methylenecyclopropanes

ivySCI AI Smartly Parses PDF, Answers Researchers' Questions, and Helps You Understand Papers in Seconds

Journal Info

Category	Quartile
CHEMISTRY, ORGANIC	2