无机化学出版无机化学各个阶段​​的基础研究。涵盖范围包括关于结构和热力学、动力学、无机反应机制、生物无机化学以及有机金属化学、固态现象和化学键合理论的相关方面的定量研究的实验和理论报告。重点放在重要的新化合物和已知化合物的合成、结构、热力学、反应性、光谱学和键合特性上。

The journal "Inorganic Chemistry" focuses on fundamental research in the field of inorganic chemistry. It covers quantitative studies related to structure and thermodynamics, kinetics, inorganic reaction mechanisms, bioinorganic chemistry, organometallic chemistry, solid-state phenomena, and chemical bonding theory. The emphasis is on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding characteristics of both important new compounds and known compounds.

《Inorganic Chemistry》期刊专注于无机化学领域的基础研究，涵盖了结构与热力学、动力学、无机反应机制、生物无机化学、有机金属化学、固态现象以及化学键合理论等方面的定量研究。期刊重点关注重要新化合物及已知化合物的合成、结构、热力学、反应性、光谱学和键合特性等内容。

Inorganic Chemistry

A facile one-step strategy has been developed for preparing monodisperse CeO(2) mesoporous spheres with high surface areas, uniform size distributions, and well-defined pore topologies. These mesoporous spheres have been demonstrated to be catalytically stable and active for CO oxidation.

Xin Liang

Junjia Xiao

Biaohua Chen

Yadong Li

Inorg. Chem.

Catalytically Stable and Active CeO2Mesoporous Spheres

催化稳定且活性高的CeO2介孔球

This work complements our recent discovery of new phases derived from zirconium perchlorate by addition of hydrogen peroxide. Here, we investigate analogous reactions with hafnium perchlorate, which is found to have modifications of the Clearfield–Vaughan tetramer (CVT). For hafnium perchlorate derivatives, we find distorted versions of CVT by X-ray diffraction and study the reaction solutions by SAXS, Raman spectroscopy, and ESI-MS. Furthermore, we investigate mixed Hf–Zr solution and solid phases and find the latter resemble the zirconium family at low Hf concentrations and the hafnium family at higher hafnium contents.

James A. Sommers

Danielle C. Hutchison

Nicolas P. Martin

Lauren Palys

Jenn M. Amador

Douglas A. Keszler

May Nyman

Differentiating Zr/HfIV Aqueous Polyoxocation Chemistry with Peroxide Ligation

过氧化物配位区分Zr/HfIV水合多氧阳离子化学

A powerful and attractive route to develop novel photocatalysts for C–N bond formation involves the use of pyrrolidine as the substrate and cocatalyst simultaneously. Herein, a new polyoxometalate (POM)-based metal–organic framework, namely, [Ni6(OH)3(H2O)9(DPNDIH)(SiW9O34)]2·2H2O (SiW9Ni6-DPNDI) (DPNDI = N,N′-di(4-pyridyl)-1,4,5,8-naphthalenediimide), was prepared by incorporating a Ni6 cluster-substituted POM anion and a photosensitizer (DPNDI) into a framework. The anion···π interactions and covalent bonds between SiW9Ni6 and DPNDI are beneficial for the consecutive electron separation and transfer. Under visible-light irradiation, DPNDI can be easily excited to generate radical species DPNDI* that could be further excited in the presence of the electron donor pyrrolidine for the inert O2 activation. SiW9Ni6-DPNDI showed a high efficiency in the photocatalysis of C–N bond formation under a mild condition by the synergy of DPNDI and SiW9Ni6. The results of the reaction were confirmed by gas chromatography and 1H NMR. In addition, SiW9Ni6-DPNDI exhibited a high sustainability without an obvious change in yields after five cycles.

Jie Li

Jiachen jiao

Jiangnan Chang

Mingxue Li

Qiuxia Han

Visible-Light-Driven C–N Bond Formation by a Hexanickel Cluster Substituted Polyoxometalate-Based Photocatalyst

Here, we report a series of two-dimensional lanthanide metal-organic frameworks Ln-DBTPA (where DBTPA = 2,5-dibromoterephthalic acid and Ln = Tb (1), Eu (2), or Gd (3)) showing a unique turn-up responsiveness toward ultraviolet (UV) radiation. The luminescence enhancement was derived from the accumulated radicals that can promote the intersystem crossing process. The compound 1 shows an ultralow detection limit of 9.1 × 10-9 J toward UV radiation, representing a new type of luminescent UV detectors.

Sida Zhang

Lixi Chen

Jian Xie

Yugang Zhang

Feng Huang

Xia Wang

Kai Li

Fuwan Zhai

Qian Yang

Lanhua Chen

Yaxing Wang

Xing Dai

Zhifang Chai

Shuao Wang

Turn-up Luminescent Sensing of Ultraviolet Radiation by Lanthanide Metal–Organic Frameworks

The heterobimetallic actinide compound UO(2)Ce(H(2)O)[C(6)H(4)(PO(3)H)(2)](2)·H(2)O was prepared via the hydrothermal reaction of U(VI) and Ce(IV) in the presence of 1,2-phenylenediphosphonic acid. We demonstrate that this is a kinetic product that is not stable with respect to decomposition to the monometallic compounds. Similar reactions have been explored with U(VI) and Ce(III), resulting in the oxidation of Ce(III) to Ce(IV) and the formation of the Ce(IV) phosphonate, Ce[C(6)H(4)(PO(3)H)(PO(3)H(2))][C(6)H(4)(PO(3)H)(PO(3))]·2H(2)O, UO(2)Ce(H(2)O)[C(6)H(4)(PO(3)H)(2)](2)·H(2)O, and UO(2)[C(6)H(4)(PO(3)H)(2)](H(2)O)·H(2)O. In comparison, the reaction of U(VI) with Np(VI) only yields Np[C(6)H(4)(PO(3)H)(2)](2)·2H(2)O and aqueous U(VI), whereas the reaction of U(VI) with Pu(VI) yields the disordered U(VI)/Pu(VI) compound, (U(0.9)Pu(0.1))O(2)[C(6)H(4)(PO(3)H)(2)](H(2)O)·H(2)O, and the Pu(IV) phosphonate, Pu[C(6)H(4)(PO(3)H)(PO(3)H(2))][C(6)H(4)(PO(3)H)(PO(3))]·2H(2)O. The reactions of Ce(IV) with Np(VI) yield disordered heterobimetallic phosphonates with both M[C(6)H(4)(PO(3)H)(PO(3)H(2))][C(6)H(4)(PO(3)H)(PO(3))]·2H(2)O (M = Ce, Np) and M[C(6)H(4)(PO(3)H)(2)](2)·2H(2)O (M = Ce, Np) structures, as well as the Ce(IV) phosphonate Ce[C(6)H(4)(PO(3)H)(PO(3)H(2))][C(6)H(4)(PO(3)H)(PO(3))]·2H(2)O. Ce(IV) reacts with Pu(IV) to yield the Pu(VI) compound, PuO(2)[C(6)H(4)(PO(3)H)(2)](H(2)O)·3H(2)O, and a disordered heterobimetallic Pu(IV)/Ce(IV) compound with the M[C(6)H(4)(PO(3)H)(PO(3)H(2))][C(6)H(4)(PO(3)H)(PO(3))]·2H(2)O (M = Ce, Pu) structure. Mixtures of Np(VI) and Pu(VI) yield disordered heterobimetallic Np(IV)/Pu(IV) phosphonates with both the An[C(6)H(4)(PO(3)H)(PO(3)H(2))][C(6)H(4)(PO(3)H)(PO(3))]·2H(2)O (M = Np, Pu) and An[C(6)H(4)(PO(3)H)(2)](2)·2H(2)O (M = Np, Pu) formulas.

Juan Diwu

Justin J. Good

Victoria H. DiStefano

Thomas E. Albrecht-Schmitt

Deviation Between the Chemistry of Ce(IV) and Pu(IV) and Routes to Ordered and Disordered Heterobimetallic 4f/5f and 5f/5f Phosphonates

Yufei Wang

Shuang Liu

Junyao Pan

Haoyang Zhang

Binyu Wang

Wenfu Yan

MER Zeolite with Remarkable Pb2+ and Cd2+ Removal Capability Cost-Effectively Synthesized from Postprocessed Natural Stellerite

MER沸石具有显著的Pb2+和Cd2+去除能力，从后处理的天然辉沸石中经济高效地合成

Nikolia Lalioti

Eleni Zygouri

Vassilis Nastopoulos

Nikos Panagiotou

Carlos D. S. Brites

Luis D. Carlos

Julio Corredoira-Vázquez

Vassilis Tangoulis

Luminescent Thermometer Based on a Praseodymium(iii) Cyanide-Based Metal–Organic Framework

基于镨(iii)氰化物金属-有机框架的发光温度计

Metal-organic frameworks (MOFs) with adjustable structures, diverse chemical functionalities, and excellent CO

Kang-Le Xie

Li-Ping Wu

Ya-Qing Liao

Jun-Jie Hu

Kang-Qiang Lu

He-Rui Wen

Jin-Rong Huo

Highly Stable Lanthanide-Organic Frameworks Based on {Ln6O8} Clusters with Photocatalytic Reduction of CO2 to CO

基于{Ln6O8}簇的高稳定性镧系有机框架及其在光催化还原CO2为CO中的应用

The electric conductivity and charge transport efficiency of metal-organic frameworks (MOFs) dictate the effective utilization of built-in redox centers and electrochemical redox kinetics and therefore electrochemical performance. Reticular chemistry and the tunable microcosmic shape of MOFs allow for improving their electric conductivity and charge transfer efficiency. Herein, we synthesized two Ni-MOFs (Ni-tdc-bpy and Ni-tdc-bpe) by the solvothermal reaction of Ni

Xinxin Hang

Xiaoju Wang

Jiaxin Chen

Meng Du

Yangyang Sun

Yong Li

Huan Pang

Enhancing the Electrochemical Energy Storage of Metal–Organic Frameworks: Linker Engineering and Size Optimization

增强金属有机框架的电化学储能：连接子工程与尺寸优化

Trivalent actinide expanded porphyrin complexes have been of synthetic interest since the isolation of the series of trivalent lanthanide texaphyrin complexes in 1992, however, synthesis of these actinide-based complexes has not yet been achieved. In this work, a computational study with relativistic density functional theory was performed to determine how trivalent actinide ions (Ac

Meagan S. Oakley

Georg Schreckenbach

Trends in Methanol-Solvated Actinide Ions and Actinide Expanded Porphyrin Complexes

甲醇溶剂化锕系离子与锕系扩展卟啉配合物的研究趋势

Abbreviation	Inorg. Chem.
Journal Impact	4.25
Quartiles(Global)	CHEMISTRY, INORGANIC & NUCLEAR(Q1)

ISSN	0020-1669, 1520-510X
h-index	255
Top Journals	Yes

Publication Information	Publisher: American Chemical Society，Publishing cycle: Biweekly，Journal Type: journal，Open Access Journals: No
Basic data	Year of publication: 1962，Proportion of original research papers: 100.00%，Self Citation Rate:11.60%， Gold OA Rate: 7.49%
Average review cycle	网友分享经验：平均2.1个月
Average recruitment ratio	网友分享经验：较难

Inorganic Chemistry

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