Nickel Polyene(yl) Complexes Synthesized from a Dinuclear Ni(I) Compound and (Multi)cyclic Polyenes

2024-9-13

Direct Detection of Pt(IV) Phenyl Complexes upon Intermolecular Oxidative Addition of Aryl Halides and Selective Csp³–I versus Csp²–Csp³ and Csp³–Csp³ Bonds Reductive Elimination from N-Heterocyclic Carbene Pt(IV) Phenyl Complexes

2024-9-13

Installation of Copper(I) and Silver(I) Sites into TREN-Based Porous Organic Cages via Postsynthetic Metalation

2024-9-12

Tantalum Catalyzed Hydroaminoalkylation Enables a Telescoping Catalytic Reaction Sequence for the Synthesis of Benzoannulated Indolizidines and Quinolizidines

2024-9-12

Flash Communication: Ti-Catalyzed “Interrupted” Cascading Hydroamination of 1,6- and 1,7-En-ynes

2024-9-12

Bis(benzimidazolin-2-ylidenes): Exploring the Impact of Ligand Properties in the Nickel-Catalyzed Suzuki–Miyaura Coupling

2024-9-12

Rhodium-Catalyzed Arene Alkenylation: Selectivity and Reaction Mechanism as a Function of In Situ Oxidant Identity

2024-9-12

Cobalt-Complexed Acetylenic Tetrads, a Molecular Scaffold for Quadruple Ionic Functionalization Reactions

2024-9-12

Synthesis of Cubic [Mo₃S₄M] (M = Rh, Ir) Clusters for the Borylation of C–H Bonds in Aromatic Compounds

2024-9-11

Mechanistic Insights into Rh-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Silazanes: The Origin of Enantioselectivity

2024-9-11

Investigating the Effects of Pulsed LED Irradiation in Photoredox Catalysis: A Pilot Study

2024-9-10

Flash Communication: A Ferrous Adduct of a Phosphanylidene-σ⁴-phosphorane

2024-9-10

Metal-Rich Fused Clusters: Syntheses, Structures, and Bonding of Heteronuclear Condensed Metallaboranes

2024-9-9

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2024-9-9

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2024-9-9

A Computational Study of Gold(I)-Catalyzed Isomerization of Cyclooctyne: A Case Study on the Mechanism of C(sp³)–H Insertion by Cationic Gold Alkyne Complexes and Model Studies

2024-9-6

Coordination Ability of Phosphavinyl(oxo and thioxo)phosphoranes (P═C–P═X; X = O, S) toward Transition Metals

2024-9-6

Tuning the Electronic Properties of Azophosphines as Ligands and Their Application in Base-Free Transfer Hydrogenation Catalysis

2024-9-6

Impact of the Olefin and Diazene Structure on the Heterofunctional Azo Metathesis Catalyzed by the First-Generation Grubbs Catalyst

2024-9-5

Lewis Base and Metal Cation-Assisted Isomerization of Disilyne

2024-9-5

Bimetallic Dimethyl Aluminum for Ring-Opening Polymerization of ε-Caprolactone: Restricted Rotation for Enhanced Metal Cooperativity

2024-9-5

Synthesis, Characterization, and Catalytic CO₂ Reduction Reactivity of Ruthenium CNC Pincer Complexes Containing Macrocyclic or Long Chain Wingtips

2024-9-4

Ir-Catalyzed Selective Reductive N-Formylation and Transfer Hydrogenation of N-Heteroarenes

2024-9-3

A Rigidified Macrocyclic Grubbs Complex: A Rare Example of <i>In</i>- and <i>Out</i>-Isomers that Show a Dramatic Difference in Catalytic Reactivity

2024-9-3

Inverse Isotope Effect for Aldehyde Hydrosilylation Catalyzed by a Hydrido–Silyl–Iridium(III) Complex

2024-9-3

Pd-PEPPSI Catalyzed Dehydrogenative Oxidation of Alcohols to Carboxylic Acids: An Experimental and Theoretical Study

2024-8-30

Oxidation-Induced Ligand Swap: Oxygen Insertion into a Cobalt-Phosphine Complex

2024-8-29

Surprising Syntheses of Reduced-Arene Inverse Sandwich Complexes of Thorium: (Cp″₂Th)₂(<i>μ</i>–<i>η</i>⁶:<i>η</i>⁶-C₆H₅R) [R = H, Me; Cp″ = C₅H₃(SiMe₃)₂]

2024-8-29

Diazo Decomposition and Carbene Transfer Mediated by a Pincer Gold(III) Complex

2024-8-26

True Homogeneous “Ligand-Free” Catalysis in Mizoroki–Heck Mono- and Double Arylations with Nonreactive Aryl Chlorides

2024-8-26

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2024-8-26

Shining Light on Organometallic Chemistry

2024-8-26

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2024-8-26

Electronic Tunability of Ruthenium Formyl and Hydroxymethyl Intermediates Relevant to Sustainable CO-to-Methanol Conversion

2024-8-26

Catalytic Synthesis and Cyclometalation of (4-Ferrocenylphenyl)pyridines

2024-8-24

Electron-Poor Iridium Pincer Complexes as Dehydrogenation Catalysts: Investigations into Deactivation through Formation of N₂, CO, and Hydride Complexes

2024-8-24

Heterogeneous Organochromium Catalysts for Stereoselective Isoprene Polymerization

2024-8-24

Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me₃SiCF₃ and Me₃SiCF₂H

2024-8-22

Multisite Ligand Noninnocence of (Cp^N3)Fe(CO)₃⁺ with Exogenous Hydride Donors: Kinetics and Mechanism

2024-8-22

Bidentate Phosphine Ligand Impacts on Previously Inaccessible Five-Membered N-Heteroaryne Formation and Functionalization

2024-8-17

Effects of Substituted Triarylphosphine Ligands on Electron Transfer in [(<i>p</i>-Cymene)Ru] Complexes

2024-8-17

Alumanyl Reduction, Reductive Coupling and C–H Isomerization of Organic Nitriles

2024-8-16

Rh → Sb Interactions Supported by Tris(8-quinolyl)antimony Ligands

2024-8-15

Use of PCCP Ligands with a <i>P</i>-Ph(alkyl) Group in Chromium-Catalyzed Ethylene Tri-/Tetramerization

2024-8-14

M^IV/Co^–I (M = Zr, Hf) Bis(phosphinoamide) Complexes with η⁶- and η⁴-Arenes

2024-8-14

Synthesis of Quinoline-Based Pt–Sb Complexes with L- or Z-Type Interaction: Ligand-Controlled Redox via Anion Transfer

2024-8-13

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2024-8-12

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2024-8-12

Pioneers and Influencers in Organometallic Chemistry: Alexander Nesmeyanov (1899–1980). Carbon and Hydrogen Are Good but What about the Other 100 Elements?

2024-8-12

Mechanistic Studies on Rh(III)-Catalyzed Defluorinative Annulation of N-Sulfonylarylamides with Ethyl 2-Diazo-3,3,3-Trifluoropropanoates

2024-8-12