来自整个化学科学领域的高影响力评论之家。

Chemical Society Reviews is a high-impact review journal covering the entire field of chemical sciences, dedicated to providing the latest research findings and in-depth analyses.

《Chemical Society Reviews》是一个涵盖整个化学科学领域的高影响力评论期刊，致力于提供最新的研究成果和深入的分析。

Chemical Society Reviews

A comprehensive summary of the stability of electrocatalytic OER will provide insight into electrocatalyst design and device optimization for industrial applications.

HuangJingWei Li

Yu Lin

Junyuan Duan

Qunlei Wen

Youwen Liu

Tianyou Zhai

Stability of electrocatalytic OER: from principle to application

电催化OER的稳定性：从原理到应用

Metal-organic frameworks (MOFs) are constructed from metal ions/clusters coordinated by organic linkers (or bridging-ligands). The hallmark of MOFs is their permanent porosity, which is frequently found in MOFs constructed from metal-clusters. These clusters are often formed in situ, whereas the linkers are generally pre-formed. The geometry and connectivity of a linker dictate the structure of the resulting MOF. Adjustments of linker geometry, length, ratio, and functional-group can tune the size, shape, and internal surface property of a MOF for a targeted application. In this critical review, we highlight advances in MOF synthesis focusing on linker design. Examples of building MOFs to reach unique properties, such as unprecedented surface area, pore aperture, molecular recognition, stability, and catalysis, through linker design are described. Further search for application-oriented MOFs through judicious selection of metal clusters and organic linkers is desirable. In this review, linkers are categorized as ditopic (Section 1), tritopic (Section 2), tetratopic (Section 3), hexatopic (Section 4), octatopic (Section 5), mixed (Section 6), desymmetrized (Section 7), metallo (Section 8), and N-heterocyclic linkers (Section 9).

Weigang Lu

Zhangwen Wei

Zhi-Yuan Gu

Tian-Fu Liu

Jinhee Park

Jihye Park

Jian Tian

Muwei Zhang

Qiang Zhang

Thomas Gentle III

Mathieu Bosch

Hong-Cai Zhou

Chem. Soc. Rev.

Tuning the structure and function of metal–organic frameworks via linker design

Adsorptive separation is very important in industry. Generally, the process uses porous solid materials such as zeolites, activated carbons, or silica gels as adsorbents. With an ever increasing need for a more efficient, energy-saving, and environmentally benign procedure for gas separation, adsorbents with tailored structures and tunable surface properties must be found. Metal-organic frameworks (MOFs), constructed by metal-containing nodes connected by organic bridges, are such a new type of porous materials. They are promising candidates as adsorbents for gas separations due to their large surface areas, adjustable pore sizes and controllable properties, as well as acceptable thermal stability. This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorption in rigid and flexible MOFs. Based on possible mechanisms, selective adsorptions observed in MOFs are classified, and primary relationships between adsorption properties and framework features are analyzed. As a specific example of tailor-made MOFs, mesh-adjustable molecular sieves are emphasized and the underlying working mechanism elucidated. In addition to the experimental aspect, theoretical investigations from adsorption equilibrium to diffusion dynamics via molecular simulations are also briefly reviewed. Furthermore, gas separations in MOFs, including the molecular sieving effect, kinetic separation, the quantum sieving effect for H2/D2 separation, and MOF-based membranes are also summarized (227 references).

Jian-Rong Li

Ryan J. Kuppler

Selective gas adsorption and separation in metal–organic frameworks

Metal–organic frameworks (MOFs, also known as porous coordination polymers or PCPs) are an emerging class of porous materials constructed from metalcontaining nodes (also known as secondary building units, or SBUs) and organic linkers. Due to their structural and functional tunability, the area of MOFs has become one of the fastest growing fields in chemistry. This is demonstrated through the ever-escalating number of structures, publications, and citations emerging, as well as by the constant expansion of research scope and researcher engagements. This almost unprecedented surge in MOF research can be ascribed to the following five developments: (1) advances in cluster chemistry, (2) maturation of organic synthesis pertinent to ligand preparation and post-synthetic modification, (3) improvement in structure determination, particularly through X-ray crystallography, and development of hardand software for evaluation of sorption properties, (4) interdisciplinary growth of MOF research with its neighboring fields, and (5) the ever-expanding potential in applications. The MOF field has recently been reviewed extensively. In 2009, the first themed issue of Chemical Society Reviews dedicated to MOFs was published and it has been a tremendous success, as evidenced by the record number of citations it has received. Additional themed issues and monographs focusing on this research area have also been published elsewhere. Following on from these a Department of Chemistry, Texas A&M University, College Station, TX 77842-3012, USA. E-mail: zhou@chem.tamu.edu; Fax: +1 979 845 1595; Tel: +1 979 845 4034 b Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan. E-mail: kitagawa@icems.kyoto-u.ac.jp

Hong-Cai “Joe” Zhou

Susumu Kitagawa

Metal–Organic Frameworks (MOFs)

New materials are prerequisite for major breakthrough applications influencing our daily life, and therefore are pivotal for the chemical industry. Metal-organic frameworks (MOFs) constitute an emerging class of materials useful in gas storage, gas purification and separation applications as well as heterogeneous catalysis. They not only offer higher surface areas and the potential for enhanced activity than currently used materials like base metal oxides, but also provide shape/size selectivity which is important both for separations and catalysis. In this critical review an overview of the potential applications of MOFs in the chemical industry is presented. Furthermore, the synthesis and characterization of the materials are briefly discussed from the industrial perspective (88 references).

Alexander U. Czaja

Natalia Trukhan

Ulrich Müller

Industrial applications of metal–organic frameworks

Ligand-protected metal nanoclusters are an emerging class of nanomaterials at the interface of the atomic and plasmonic regimes with unique photophysical and electrochemical properties, leading to diverse applications.

Subarna Maity

Sarita Kolay

Sikta Chakraborty

Aarti Devi

None Rashi

Amitava Patra

A comprehensive review of atomically precise metal nanoclusters with emergent photophysical properties towards diverse applications

面向多样化应用的具有新兴光物理性质的原子精确金属纳米团簇的综合评述

Catalytic asymmetric conjugate additions of carbon nucleophiles have emerged as a potent tool for constructing multi-stereogenic molecules with precise stereochemical control. This review explores the concept of diastereodivergence in such reactions, focusing on strategies to achieve selective access to diverse diastereomeric products upon carbon-carbon bond formation. Drawing from a rich array of examples, we delve into key approaches for controlling the stereochemical outcome of these transformations, including alteration of alkene geometry, fine-tuning of reaction parameters, synergistic catalysis, and isomerization of conjugate adducts. Additionally, we highlight the iterative strategies for conjugate additions, showcasing their potential for diastereodivergent synthesis of methyl-branched stereocenters in 1,3-relationships. By presenting a concentrated overview of this significant topic, this review aims to provide valuable insights into the design and execution of stereodivergent catalytic conjugate additions, offering new avenues for advancing stereoselective synthesis and structural diversity in organic synthesis.

Byungjun Kim

Hooseung Lee

Ilwoo Song

Sarah Yunmi Lee

Diastereodivergence in catalytic asymmetric conjugate addition of carbon nucleophiles

碳亲核试剂催化不对称共轭加成中的非对映选择性

Selective hydrogenation has been employed extensively to produce value-added chemicals and fuels, greatly alleviating the problems of fossil resources and green synthesis. However, the design and synthesis of highly efficient catalysts, especially those that are inexpensive and abundant in the earth's crust, is still required for basic research and subsequent industrial applications. In recent years, many studies have revealed that the rational design and synthesis of heterogeneous catalysts can efficaciously improve the catalytic performance of hydrogenation reactions. However, the relationship between nonprecious metal catalysts and hydrogenation performance from the perspective of different catalytic systems still remains to be understood. In this review, we provide a comprehensive and systematic overview of the recent advances in the synthesis of nonprecious metal catalysts for heterogeneous selective hydrogenation reactions including thermocatalytic hydrogenation/transfer hydrogenation, photocatalytic hydrogenation and electrocatalytic reduction. In addition, we also aim to provide a clear picture of the recent design strategies and proposals for the nonprecious metal catalysed hydrogenation reactions. Finally, we discuss the current challenges and future research opportunities for the precise design and synthesis of nonprecious metal catalysts for selective hydrogenation reactions.

Wanbing Gong

Jun Ma

Guangyu Chen

Yitao Dai

Ran Long

Huijun Zhao

Yujie Xiong

Unlocking the catalytic potential of heterogeneous nonprecious metals for selective hydrogenation reactions

解锁非贵金属在选择性氢化反应中的催化潜力

The core of clean energy technologies such as fuel cells, water electrolyzers, and metal-air batteries depends on a series of oxygen and hydrogen-based electrocatalysis reactions, including the oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), which necessitate cost-effective electrocatalysts to improve their energy efficiency. In the recent decade, complex metal oxides (beyond simple transition metal oxides, spinel oxides and ABO

Yinlong Zhu

Zheng Tang

Lingjie Yuan

Bowen Li

Zongping Shao

Wanlin Guo

Beyond conventional structures: emerging complex metal oxides for efficient oxygen and hydrogen electrocatalysis

超越传统结构：新兴复杂金属氧化物用于高效氧和氢电催化

Photon avalanche (PA)-where the absorption of a single photon initiates a 'chain reaction' of additional absorption and energy transfer events within a material-is a highly nonlinear optical process that results in upconverted light emission with an exceptionally steep dependence on the illumination intensity. Over 40 years following the first demonstration of photon avalanche emission in lanthanide-doped bulk crystals, PA emission has been achieved in nanometer-scale colloidal particles. The scaling of PA to nanomaterials has resulted in significant and rapid advances, such as luminescence imaging beyond the diffraction limit of light, optical thermometry and force sensing with (sub)micron spatial resolution, and all-optical data storage and processing. In this review, we discuss the fundamental principles underpinning PA and survey the studies leading to the development of nanoscale PA. Finally, we offer a perspective on how this knowledge can be used for the development of next-generation PA nanomaterials optimized for a broad range of applications, including mid-IR imaging, luminescence thermometry, (bio)sensing, optical data processing and nanophotonics.

Marcin Szalkowski

Agata Kotulska

Magdalena Dudek

Zuzanna Korczak

Martyna Majak

Lukasz Marciniak

Malgorzata Misiak

Katarzyna Prorok

Artiom Skripka

P. James Schuck

Emory M. Chan

Artur Bednarkiewicz

Advances in the photon avalanche luminescence of inorganic lanthanide-doped nanomaterials

无机镧系掺杂纳米材料光子雪崩发光的研究进展

短名	Chem. Soc. Rev.
Journal Impact	40.45
国际分区	CHEMISTRY, MULTIDISCIPLINARY(Q1)
期刊索引	SCI Q1中科院 1 区

ISSN	0306-0012, 1460-4744
h-index	635
国内分区	化学(1区)化学化学综合(1区)
Top 期刊	是

涉及主题	化学物理材料科学有机化学工程类生物纳米技术量子力学生物化学计算机科学催化作用
出版信息	出版商: Royal Society of Chemistry，出版周期: Monthly，期刊类型: journal，开源期刊: 否
基本数据	创刊年份: 1972，原创研究文献占比: 0.00%，自引率:1.20%， Gold OA占比: 26.20%
平均审稿周期	网友分享经验：平均6.0个月
平均录用比例	网友分享经验：多是约稿

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